计算过程如下：
1，通过由主角中心raycast一条竖直射线获得主角所在处地面法线，用作主角的newUp。
2，根据主角forward和newUp计算newForward。
3，使用Quaternion.LookRotation (newForward, newUp)获得主角新的rotation。
结果如图：
代码：
//note, the code here suppose our character use a capsuleCollider and the floors‘ layerMask is "floor"..
//..if yours‘ is not, you should make some change.
RaycastHit hitInfo;
Vector3 capsuleColliderCenterInWorldSpace=GetComponent<CapsuleCollider> ().transform.TransformPoint (GetComponent<CapsuleCollider>().center);
bool isHit=Physics.Raycast (capsuleColliderCenterInWorldSpace,new Vector3(0f,-1f,0f),out hitInfo,100f,LayerMask.GetMask("floor"));
Vector3 forward=GetComponent<Rigidbody>().transform.forward;
Vector3 newUp;
if (isHit) {
newUp = hitInfo.normal;
} else {
newUp = Vector3.up;
}
Vector3 left = Vector3.Cross (forward,newUp);//note: unity use left-hand system, and Vector3.Cross obey left-hand rule.
Vector3 newForward = Vector3.Cross (newUp,left);
Quaternion oldRotation=GetComponent<Rigidbody>().transform.rotation;
Quaternion newRotation = Quaternion.LookRotation (newForward, newUp);
float kSoftness=0.1f;//if do not want softness, change the value to 1.0f
GetComponent<Rigidbody> ().MoveRotation (Quaternion.Lerp(oldRotation,newRotation,kSoftness));
unity, 让主角头顶朝向等于地面法线（character align to surface normal）
原文：http://www.cnblogs.com/wantnon/p/4380554.html