解决方法：
将hibernate.cfg.xml 的开头改为：
<?xml version="1.0" encoding="UTF-8"?>
<!DOCTYPE hibernate-configuration PUBLIC
"-//Hibernate/Hibernate Configuration DTD 3.0//EN"
"http://www.hibernate.org/dtd/hibernate-configuration-3.0.dtd">[Classpath]: Could not parse configuration: ……\hibernate.cfg.xml
原文：http://blog.csdn.net/zc123456zzc/article/details/45534883